高性能 Thiol 单体s Series: SINOMER® BMES, BMPT, PETMP, PM839

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高性能 Thiol 单体s Series: SINOMER® BMES, BMPT, PETMP, PM839

From high-index optical lenses to low-temperature epoxy curing — four thiol products to solve your formulation challenges


Polymercaptan, mercaptan, and polythiol compounds play an irreplaceable role in optical materials, UV curing, low-temperature curing, metal adhesion, and more, thanks to their unique reactivity — they readily undergo thiol-ene and thiol-epoxy click reactions with isocyanates, epoxies, and unsaturated double bonds. 中固化学集团 offers four 高性能 thiol products covering a wide range of applications, from high-index lenses to UV anti‑oxygen‑inhibition and low‑temperature epoxy curing.


1. SINOMER® BMES — Optical‑Grade Difunctional Thioether 单体

Chemical name:     Bis(2-mercaptoethyl) sulfide
CAS No.:    
 3570-55-6


BMES is a difunctional mercaptan containing two thiol groups, developed for high‑index optical materials.


Key advantages:

  • High refractive index: Up to 1.59–1.60, ideal for 1.60+ index resin lenses.

  • Very low color: APHA ≤ 15, excellent light transmittance, no yellowing.

  • Low moisture content: ≤ 1000 ppm, minimizing bubble and haze formation.

  • Low viscosity: Liquid form, easy to process and blend.


Applications:

  • High‑index optical lenses: Core 单体 for 1.60+ index lenses — thinner, lighter, and clearer.

  • Specialty anti‑corrosion 涂料: Thiol groups form strong bonds with metal ions, creating a protective barrier on metal surfaces against corrosive environments.

  • Organic synthesis intermediate: Key building block for sulfur‑containing pharmaceuticals, agrochemicals, and high‑performance polymers; also used to synthesize luminescent polynuclear gold(I) phosphine complexes.

  • Coordination chemistry & catalysis: Acts as a bidentate sulfur ligand to form stable metal complexes with nickel, iron, etc., for catalytic hydrogenation and other reactions.


2. SINOMER® BMPT — High‑Index 单体 for 1.60/1.67 Lenses

Chemical name:  2,3-bis((2-mercaptoethyl)thio)-1-propanethiol;1,2-Bis[(2-mercaptoethyl)thio]-3-mercaptopropane

CAS No:  131538-00-6 

BMPT is a multifunctional mercaptan specifically developed for 1.60 and 1.67 high‑index resin lenses. It reacts with isocyanates or epoxies via thiol‑ene or thiol‑epoxy reactions to form highly crosslinked optical polymers.


Product highlights:

  • High refractive index (1.63–1.64), perfectly matched for 1.60/1.67 lenses

  • High Abbe number, sharp images with no chromatic aberration

  • High impact resistance, lenses resist breakage

  • Good dyeability, enabling various tinted lens colors

  • Compatible with precision progressive lens designs


Main applications:

  • 1.67 high‑index ophthalmic lenses

  • High‑index optical lens elements

  • Precision optical lens UV adhesives (for lens assembly and bonding)

  • Optical 涂料


3. SINOMER® PETMP — Tetrafunctional High‑Purity Thiol Crosslinker

Chemical name:     Pentaerythritol Tetra(3-Mercaptopropionate)
CAS No.:     
7575-23-7

PETMP is a tetrafunctional polythiol with 25–27% mercapto content, refractive index ≥ 1.529, extremely low color (Hazen ≤ 15), and much lower odor than traditional mercaptans.


Key features:

  • Fast cure & oxygen inhibition resistance: Acts as a co‑initiator in UV radical systems to overcome surface oxygen inhibition.

  • Low shrinkage: Thiol‑ene/epoxy click polymerization exhibits much lower volume shrinkage than conventional acrylates.

  • Excellent adhesion: Thiol groups naturally bond to metals, glass, and other surfaces.

  • Low‑temperature curing: Can quickly cure epoxy resins at room temperature or even low temperatures.


Applications:

  • High‑index optical resin 单体 synthesis

  • Modifier and crosslinker for UV 涂料, inks, and adhesives

  • Acidic ion exchange catalysts

  • Low‑temperature curing agents (epoxy/isocyanate systems)


4. SINOMER® PM839 — Polymeric Mercaptan Low‑Temperature Epoxy Curing Agent

PM839 is a liquid polymercaptan curing agent that serves as a direct replacement for CAPCURE® 3-800 Curing Agent, GABEPRO GPM-800, and Toray POLYTHIOL QE-340M. It offers a mercapto equivalent ≥ 3.0 meq/g, moderate viscosity, and low total chlorine content (≤ 800 ppm).

Key features:

  • Fast low‑temperature curing: Achieves high lap shear strength within 30 minutes even at −5°C when combined with epoxy resin and DMP‑30 accelerator.

  • Excellent thin‑film cure: Particularly suitable for thin bond lines where conventional amine hardeners cure slowly.

  • Light color, low chlorine: Hazen ≤ 20, total chlorine ≤ 800 ppm, suitable for electronic‑grade applications.

  • Adjustable pot life: Gel time can be tuned by accelerator dosage.


Typical applications:

  • Low‑temperature rapid curing of epoxy resins (especially for winter construction)

  • PV silicon wafer processing (temporary bonding/debonding)

  • Jewelry and craft bonding

  • Electronic adhesives

  • Anti‑corrosion 涂料


Summary: Four Thiol Products, Each with Its Specialty


Product

Functionality

Key Features

Main Applications

BMES

2

High RI (1.59–1.60), very low color, low viscosity

Highindex lenses, anticorrosion 涂料, organic synthesis intermediate

BMPT

3

High RI (1.63–1.64), high impact resistance, high Abbe number

1.60/1.67 highindex lenses, precision lens UV adhesives, optical 涂料

PETMP

4

High purity, low odor, oxygen inhibition resistance, low shrinkage

UV 涂料/inks/adhesives crosslinker, highindex resins, lowtemp curing

PM839

3

Fast lowtemp curing, excellent thinfilm cure, low chlorine; direct replacement for CAPCURE® 3-800 / GPM-800 / QE-340M

Epoxy lowtemp curing agent, electronic adhesives, PV wafer processing, anticorrosion 涂料


中固化学集团 offers a complete polythiol product line from optical‑grade 单体s to industrial‑grade curing agents. Whether you need to increase lens refractive index or solve winter epoxy curing challenges, we have proven solutions.


Request samples or technical support: Contact our sales team for TDS, SDS, and formulation optimization assistance.


Data based on typical test results. Actual performance should be verified through laboratory trials.


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